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While it doesnt have any triggers when dealing combat damage to a player (unlike other swords such as Sword of Fire and Ice), The Masamune supplies an additional benefit: If a creature dying causes a triggered ability of this creature or an emblem you own to trigger, that ability triggers an additional time. That was rather wordy, so its worth noting a few things: 1

This concept applies directly to Lorcana, but Magic has had 30 years to solidify their color identities, and as such, subsequent set releases will likely alter Lorcanas ink identities in the years to come

Do Any White Cards Allow Me to Draw Cards When Opponents Gain Life

And fortunately for those building with this mechanic, being able to benefit from proliferate is really all the synergy you need