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The glutamate residue is linked through its side-chain carboxyl, giving a gamma-glutamyl bond rather than a standard alpha-peptide bond, which is why the molecule resists most intracellular peptidases and is cleaved chiefly by gamma-glutamyl transpeptidase at the cell surface
Uchikawa, E., Chen, Z., Xiao, G
doi: 10.1136/bmj.d6898 13 MonamiMCandidoRPintaudiBTargherGMannucciEof the SID-AMD joint panel for Italian Guidelines on Treatment of Type 2 Diabetes
GRX-SG is then reduced in the presence of GSH, GR and NADPH
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