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While the second-order rate constants of PfGrx C88S and PfGrx C32S/C88S for GSSG are one order of magnitude higher than for bulky roGFP2(SSG), the rate constant for the glutathionylation of PfGrx C32S/C88S by GSSG is twice that with GSSCys (Table 1) 14
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This variability explains why some users tolerate semaglutide with minimal issues while others experience more pronounced symptoms
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